AQAAS Level90 resources

AQA AS Chemistry Past Papers & Mark Schemes

Download free AQA AS Chemistry (7404) past papers, mark schemes & data sheets. Paper 1: Inorganic & Physical. Paper 2: Organic & Physical. 90 resources.

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June 2023

5 files
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AS Chemistry – Question paper (Modified A4 18pt) (AS) : Paper 2 Organic and physical chemistry – June 2023

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AS Chemistry – Question paper (Modified A4 18pt) (AS) : Paper 1 Inorganic and physical chemistry – June 2023

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AS Chemistry – Question paper (Modified A3 36pt) (AS) : Paper 2 Organic and physical chemistry – June 2023

Question Paper
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AS Chemistry – Question paper (Modified A3 36pt) (AS) : Paper 1 Inorganic and physical chemistry – June 2023

Question Paper
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AS Chemistry – Question paper (AS) : Paper 2 Organic and physical chemistry – June 2023

Question Paper

June 2022

5 files
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AS Chemistry – Question paper (Modified A4 18pt) (AS) : Paper 2 Organic and physical chemistry – June 2022

Question Paper
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AS Chemistry – Question paper (Modified A4 18pt) (AS) : Paper 1 Inorganic and physical chemistry – June 2022

Question Paper
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AS Chemistry – Question paper (Modified A3 36pt) (AS) : Paper 2 Organic and physical chemistry – June 2022

Question Paper
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AS Chemistry – Question paper (Modified A3 36pt) (AS) : Paper 1 Inorganic and physical chemistry – June 2022

Question Paper
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AS Chemistry – Question paper (AS) : Paper 2 Organic and physical chemistry – June 2022

Question Paper

November 2021

2 files
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AS Chemistry – Question paper (Modified A4 18pt) (AS) : Paper 1 Inorganic and physical chemistry – November 2021

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AS Chemistry – Question paper (AS) : Paper 2 Organic and physical chemistry – November 2021

Question Paper

November 2020

3 files
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AS Chemistry – Question paper (Modified A4 18pt) (AS) : Paper 2 Organic and physical chemistry – November 2020

Question Paper
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AS Chemistry – Question paper (Modified A4 18pt) (AS) : Paper 1 Inorganic and physical chemistry – November 2020

Question Paper
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AS Chemistry – Question paper (AS) : Paper 2 Organic and physical chemistry – November 2020

Question Paper

June 2019

4 files
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AS Chemistry – Question paper (Modified A4 18pt) (AS) : Paper 2 Organic and physical chemistry – June 2019

Question Paper
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AS Chemistry – Question paper (Modified A4 18pt) (AS) : Paper 1 Inorganic and physical chemistry – June 2019

Question Paper
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AS Chemistry – Question paper (Modified A3 36pt) (AS) : Paper 2 Organic and physical chemistry – June 2019

Question Paper
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AS Chemistry – Question paper (Modified A3 36pt) (AS) : Paper 1 Inorganic and physical chemistry – June 2019

Question Paper

June 2018

2 files
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AS Chemistry – Question paper (Modified A4 18pt) (AS) : Paper 2 Organic and physical chemistry – June 2018

Question Paper
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AS Chemistry – Question paper (Modified A4 18pt) (AS) : Paper 1 Inorganic and physical chemistry – June 2018

Question Paper

June 2017

2 files
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AS Chemistry – Question paper (Modified A4 18pt) (AS) : Paper 2 Organic and physical chemistry – June 2017

Question Paper
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AS Chemistry – Question paper (Modified A4 18pt) (AS) : Paper 1 Inorganic and physical chemistry – June 2017

Question Paper

June 2016

2 files
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AS Chemistry – Question paper (Modified A4 18pt) (AS) : Paper 2 Organic and physical chemistry – June 2016

Question Paper
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AS Chemistry – Question paper (Modified A4 18pt) (AS) : Paper 1 Inorganic and physical chemistry – June 2016

Question Paper

Inorganic, Organic, and Physical Chemistry: Year One Foundations with Data Sheets

AQA AS Chemistry (specification 7404) covers the first year of the two-year A-Level course as a standalone qualification. With 90 resources including past papers and data sheets, this is one of the most extensively resourced AS subjects. Paper 1: Inorganic and Physical Chemistry (1 hour 30 minutes, 80 marks, 50%) combines inorganic chemistry with physical chemistry topics. The physical content includes atomic structure (electron configuration, mass spectrometry, ionisation energies), amount of substance (moles, empirical and molecular formulae, the ideal gas equation), bonding (ionic, covalent, metallic, intermolecular forces, shapes of molecules using VSEPR), energetics (enthalpy changes, Hess's law, bond enthalpies), and kinetics (collision theory, Maxwell-Boltzmann distribution, catalysts). The inorganic content covers periodicity (Period 3 trends), Group 2 chemistry (reactions, solubility trends), and Group 7 chemistry (halogen reactivity, halide tests, disproportionation). Paper 2: Organic and Physical Chemistry (1 hour 30 minutes, 80 marks, 50%) pairs the organic chemistry content with equilibria and redox. The organic content introduces the fundamentals of carbon chemistry — nomenclature and isomerism, alkanes (combustion, free radical substitution), halogenoalkanes (nucleophilic substitution, elimination, ozone depletion), alkenes (electrophilic addition, addition polymers), alcohols (classification, oxidation, elimination), and organic analysis (mass spectrometry, infrared spectroscopy). The physical content includes chemical equilibria (Le Chatelier's principle, the equilibrium constant Kc) and oxidation-reduction (oxidation states, redox equations, electrochemical cells). Both papers provide a data sheet containing the periodic table and selected physical constants. Questions range from short objective-style items to multi-step calculations and extended writing, with at least 20% of marks assessing mathematical skills and 15% assessing practical knowledge.

Exam Paper Structure

Paper 1Calculator ✓

Inorganic and Physical Chemistry

1 hour 30 minutes🎯 80 marks📊 50% of grade
Atomic structure and electron configurationAmount of substance (moles, gas equation)Bonding and molecular shapes (VSEPR)Energetics (Hess's law, bond enthalpies)Kinetics (collision theory, catalysts)Group 2 and Group 7 chemistry
Paper 2Calculator ✓

Organic and Physical Chemistry

1 hour 30 minutes🎯 80 marks📊 50% of grade
Organic nomenclature and isomerismAlkanes, halogenoalkanes, alkenes, alcoholsOrganic reaction mechanismsOrganic analysis (mass spec, IR spectroscopy)Equilibria (Kc, Le Chatelier's principle)Oxidation-reduction (oxidation states, redox equations)

Key Information

Exam BoardAQA
Specification Code7404
QualificationAS Level
Grading ScaleA–E
Assessment Type2 written papers (calculator allowed)
Paper 1Inorganic and Physical Chemistry (1 hr 30 min, 80 marks, 50%)
Paper 2Organic and Physical Chemistry (1 hr 30 min, 80 marks, 50%)
Data SheetPeriodic table and constants provided
Mathematical ContentAt least 20% of marks
Practical Assessment15% of marks assess practical skills
Exam SessionsJune only
Total Resources90

Key Topics in Chemistry

Topics you need to know

Atomic structure (electron configuration, ionisation energies)Amount of substance (moles, ideal gas equation)Chemical bonding and intermolecular forcesEnergetics (enthalpy, Hess's law)Kinetics (collision theory, Maxwell-Boltzmann distribution)Organic chemistry (alkanes, alkenes, halogenoalkanes, alcohols)Chemical equilibria (Kc, Le Chatelier's principle)Group 2 and Group 7 inorganic chemistry

Exam Command Words

Command wordWhat the examiner expects
CalculateWork out a numerical answer showing formula, substitution, and units — method marks are only awarded when working is visible
Draw the mechanismShow curly arrows starting from bonds or lone pairs, with intermediates and correct charges
ExplainGive chemical reasons for an observation, linking to bonding, structure, or energetic principles
IdentifyName or give the formula of a substance, functional group, or spectroscopic feature
OutlineDescribe the main steps of a process briefly — include essential detail but not full mechanistic drawings
JustifySupport a conclusion with specific chemical evidence or reasoning

Typical Grade Boundaries

GradeApproximate mark needed
A63–73%
B52–62%
C42–51%
D32–41%
E22–31%

⚠️ AS Chemistry uses 160 raw marks (80 per paper). Grade thresholds are typically lower than AS Mathematics, reflecting the conceptual difficulty of the subject.

Moles Calculations, Organic Mechanisms, and Linking Physical Chemistry to Reactions

Moles calculations underpin nearly every quantitative question in AS Chemistry. Practise until the relationships between mass, moles, molar mass, concentration, and volume are automatic: n = m/M, n = cV (with V in dm³), and the ideal gas equation pV = nRT. The most common error is unit conversion — concentration must be in mol dm⁻³, volume in dm³ for concentration calculations or m³ for the gas equation, and pressure in Pa. Write units at every step and check dimensional consistency before calculating. Organic mechanisms at AS level include free radical substitution (alkanes with halogens under UV), nucleophilic substitution (halogenoalkanes with hydroxide, cyanide, or ammonia), electrophilic addition (alkenes with HBr or Br₂), and elimination (halogenoalkanes with ethanolic KOH). For each mechanism, learn the type of bond-breaking (homolytic or heterolytic), the curly arrow notation (single-headed arrows for radicals, double-headed for ionic), and the specific conditions required. The mark scheme checks each curly arrow individually — an arrow that starts from the wrong place or points to the wrong atom loses the mark. Group chemistry questions test your ability to describe reactions and explain trends. For Group 2, the key trend is increasing reactivity down the group (lower ionisation energy → electrons lost more easily). For Group 7, the key trend is decreasing reactivity down the group (lower electronegativity → weaker ability to gain electrons). Learn the specific reactions: Group 2 metals with water, Group 2 oxides and hydroxides with acids, halogen displacement reactions. Use equations in your answers — word descriptions without balanced equations rarely score full marks. For equilibrium questions, remember that changing conditions shifts the position of equilibrium but does not change the value of Kc (unless temperature changes). Students frequently confuse these two ideas. Increasing concentration of a reactant shifts the position right but Kc stays the same. Only temperature changes alter Kc: an increase in temperature increases Kc for endothermic reactions and decreases Kc for exothermic reactions.

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